SOME TRIGONAL MINERALS
SAPPHIRE
ANKERITE
RUBY
STURMANITE
MAGNESITE
PYRARGYRITE
RHODOCHROSITE
HEMATITE
CINNABAR
ELBAITE

The trigonal system is sometimes included in the
hexagonal system as a division, called the rhombohedral division with the other hexagonal classes grouped into the hexagonal division.
However, the difference between the two divisions is large enough to merit dividing the two into two distinctive systems, albeit acknowledging their close similarities.
The hexagonal system has as its defining characteristic a six fold rotational axis or a six fold rotoinversion axis.
The trigonal system likewise has a three fold rotational axis or a three fold rotoinversion axis.
Although the six fold rotoinversion axis produces a trigonal looking crystal, that symmetry is produced by the six fold symmetry operation.
Also the classes of the trigonal system frequently use forms "belonging" to the hexagonal system.
But this kind of borrowing is allowed as
orthorhombic classes "borrow" domes, sphenoids and pinacoids from the monoclinic system.
The hexagonal and trigonal systems are unlike any of the other systems in terms of crystallographic axes.
While the other systems use three crystallographic axes, the hexagonal and trigonal systems use four axes.
The major or principle three fold or six fold axis is, of course, one of the axes.
The other three axes lie in a plane perpendicular to the principle axis.
Modern crystallographers actually ignore one of these axes and use only two of the perpendicular axes to define the crystallography of this system, see the discussion of of this matter in the
hexagonal system.
The three perpendicular axes are symmetrically spread out with 120 degrees between the positive ends of each axis.
If the axes are extended through the center, then the angle between each axes is only 60 degrees.
In the hexagonal system
there is no difference between the positive and negative poles of an axis.
However, if there exists a difference between the poles of the axes, then this would make the system trigonal as opposed to hexagonal.
The highest symmetry class in the trigonal system is the Hexagonal Scalenohedral Class.
It has 1 three fold rotoinversion axis, 3 two fold axes, 3 mirror planes parallel to the principle axis and a center.
This class, more so than the other classes of this system, has members that "borrow" forms from the more symmetrical hexagonal system's classes.
In fact, unless a crystal from this class shows rhombohedral or scalenohedral faces or rhombohedral cleavage or parting, it will be difficult to determine the crystal's true symmetry.
The Trigonal Trapezohedral Class has one of the most common minerals in the Earth's crust as its member.
Quartz crystallizes in this class, but only outwardly shows its true symmetry occasionally with the small trapezohedral faces.
The trapezohedral faces will modify the corner of the prism faces as the prism faces intersect the pyramid faces.
The corner trapezohedral face is either in the right or left side of the prism and distinguishes a right handed quartz crystal from a left handed crystal.
Both the Ditrigonal Pyramidal Class and Trigonal Pyramidal Class are hemimorphic which means they have a different top and bottom.
A typical crystal, might have a pyramid top and a pedion for a base.
In the case of tourmaline which belongs to the Ditrigonal Pyramidal Class, the top of the crystal might have a pyramid that is steep while the bottom might have a pyramid that is less inclined.
Crystals from both classes could be hard to distinguish as the only difference is the presence or absence of mirror planes.
The Rhombohedral Class only has a three fold rotoinversion axis.
Unlike other rotoinversion axis with four fold or six fold rotations, the three fold rotoinversion axis does not appear to lower its own symmetry (see classes
15,
17,
22,
24 &
30).
The three fold rotoinversion axis takes a face, rotates it 120 degrees (one third of a rotation) and then inverts it (up to down & right to left) through the crystal to the other side.
Then it rotates it again 120 degrees and inverts it again through the crystal.
Another four times through the rotoinversion operation (six in all) and it is back exactly where it started.
The result is still a trigonal looking crystal (a rhombohedron for example) with six faces, three above and three below.
The six fold rotoinversion differs from the three fold rotoinversion in the production of a perpendicular mirror plane.
The six fold rotoinversion produces a perpendicular mirror plane because the top three faces are directly above the bottom three faces.
But in the three fold rotoinversion the top three faces are rotated 60 degrees from the bottom three faces so that no perpendicular mirror plane can exist.
Calcite
 Class: 13th
 Symmetry: Bar 3 2/m
 Symmetry Elements: There is 1 three fold rotoinversion axis, 3 two fold axes, 3 mirror planes each perpendicular to one of the two fold rotational axes and a center.
 Crystallographic Axes: Three axes, all in one plane, termed a1, a2 and a3 are equal to each other, but they are either shorter or longer than the c axis.
 Angles: All angles between the positive ends of the a axes = 120 degrees.
The angle between all the a axes and the c axis = 90 degrees.
 Common Forms: The scalenohedron,
rhombohedron,
dihexagonal prism, hexagonal prism, hexagonal
dipyramid and the basal
pinacoid.
 Most Common Minerals Known to this Class: Members of the
calcite group as well as
corundum,
hematite,
bismuth,
antimony,
sturmanite,
brucite,
arsenic,
soda niter,
chabazite and
millerite among others.
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Quartz, variety
Amethyst.
 Class: 12th
 Symmetry: 3 2
 Symmetry Elements: There is 1 three fold axis and 3 two fold axes.
 Crystallographic Axes: Three axes, all in one plane, termed a1, a2 and a3 are equal to each other, but they are either shorter or longer than the c axis.
 Angles: All angles between the positive ends of the a axes = 120 degrees.
The angle between all the a axes and the c axis = 90 degrees.
 Of Note: Crystal can be left and right handed, enantiomorphic.
 Common Forms: The trigonal
trapezohedron,
rhombohedron, trigonal
prism, ditrigonal prism, trigonal
dipyramid and the basal
pinacoid.
 Most Common Minerals Known to this Class:
quartz,
tellurium
berlinite and
cinnabar.
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Dravite, a member of the
Tourmaline Group
 Class: 11th
 Symmetry: 3 m
 Symmetry Elements: There is 1 three fold axis and 3 mirror planes each parallel to the principle axis.
 Crystallographic Axes: Three axes, all in one plane, termed a1, a2 and a3 are equal to each other, but they are either shorter or longer than the c axis.
 Angles: All angles between the positive ends of the a axes = 120 degrees.
The angle between all the a axes and the c axis = 90 degrees.
 Of Note: Crystals of this group are hemimorphic, i.e., a different top and bottom.
 Common Forms: The ditrigonal pyramid,
hexagonal prism,
hexagonal pyramid, trigonal pyramid, trigonal prism, ditrigonal prism and the
pedion.
 Most Common Minerals Known to this Class: Members of the
Tourmaline Group as well as
pyrargyrite,
jarosite,
natrojarosite,
alunite and
proustite.
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Dolomite
 Class: 10th
 Symmetry: Bar 3
 Symmetry Elements: There is 1 three fold rotoinversion axis and a center.
 Crystallographic Axes: Three axes, all in one plane, termed a1, a2 and a3 are equal to each other, but they are either shorter or longer than the c axis.
 Angles: All angles between the positive ends of the a axes = 120 degrees.
The angle between all the a axes and the c axis = 90 degrees.
 Common Forms: The rhombohedron,
hexagonal prism
and the basal pinacoid.
 Most Common Minerals Known to this Class: members of the
Dolomite Group as well as
ankerite,
ilmenite,
dioptase,
willemite and
phenakite.
^
 Class: 9th
 Symmetry: 3
 Symmetry Elements: Only 1 three fold axis.
 Crystallographic Axes: Three axes, all in one plane, termed a1, a2 and a3 are equal to each other, but they are either shorter or longer than the c axis.
 Angles: All angles between the positive ends of the a axes = 120 degrees.
The angle between all the a axes and the c axis = 90 degrees.
 Of Note: Crystals of this group are hemimorphic, ie. different top and bottom.
 Common Forms: The trigonal
pyramid,
trigonal prism and the
pedion.
 Most Common Minerals Known to this Class:
Gratonite is the only somewhat common mineral known to this class.
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Isometric
 Tetragonal
 Hexagonal
 Orthorhombic
 Monoclinic
 Triclinic
 Amorphous

